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First 2 days is the Corporate Induction and is held at a city centre hotel, usually the Hilton. The rest takes place at the Training Academy on South Parade, near the corner of Headrow and Park Row.
You’re correct in that you can’t take leave during the training period. Yes, she will accrue leave and she will be able to take it when her course ends even though it runs into the following year. Her CTM will be able to organise that for her.