It would have been coupled to 195001, since 001 and 007 are the only 195/0s known to have seen passenger service. I saw the pair yesterday myself working the 1616 Liverpool - Airport.
The pair are scheduled to work 0709SuX Lime Street - Oxford Road, this is a semi-fast, although it does call at Widnes and Irlam in addition to the standard calling points of Liverpool South Parkway, Warrington Central, and Birchwood. Arrival (in P5 at Ox Road) is scheduled for 0805, and departure for 0912. Again, this is a semi-fast, and it only makes the standard semi-fast stops.
On the normal cycle you would expect there to be a 0716 Liverpool - Airport and 0850 return - I don't know why this particular journey stops short at Oxford Road. While it is resting in P5, the 0816, 0846, and 0916 CLC stoppers are required to depart P3.