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Cant say I would know off the top of me head but im guessing it would be an early/late system of around 06/700 - 14/500 then 14/500 - 21/200 sort of thing. though im sure at Waterloo they would have a night shift also.
thanks, guessed it might be somethign like that but wondered about the likely pattern of days that it may work through, and also the NR website says the relevant ticket offcie is manned 05:30 onwards, so wondered if the duty amanger comes on at the same time!