He could have sent an emergency message on his train radio.
The report says that the emergency message was only sent after the collision, and doesn't seem to mention any other message sent by the driver of the sliding train. The signaller was already aware before the collision, and had alerted the other driver. So what alerted the signaller? He should have been automatically alerted of the SPAD when the train passed the stop marker at the end of the loop, but I am not aware of anything that would have alerted him any earlier than that. So if the driver of the sliding train had sent an emergency message as soon as he realised he was in trouble, this might have allowed the driver of the train coming the other way slightly more warning. Can this emergency message be sent by just pressing a button in the cab, or does it involve having to spend time talking to the signaller? I could understand the driver not wanting to stay in the cab any longer than necessary.
Other than that, in my opinion he did the right thing by evacuating the cab and warning the passengers.