My school history has some interesting fire alarm incidents:
1) In primary school someone in my class in year 6, while on cloakroom monitor duty, decided to set the alarm off during break time. As a result the kids didn't realise for a while as it wasn't well audible on the playground, only when staff who had to vacate came out and assembled everyone like in a classic drill. The boy in question was suspended for 3 days.
2) Year 12: the alarm went off by accident when a girl took their blazer off behind an alarm point and in a way that set it off. This meant an A-Level exam had to evacuate the hall mid-way through.
3) Year 13 at the start of summer term: A drill had been planned for the afternoon. However during the lunch break, around 45 minutes before the drill was planned (planned drills were announced to everyone in advance), an electrical fault developed in one of the buildings, that, while not causing a fire, short-circuited something and automatically triggered both the fire alarm and summoned the fire brigade. The Deputy Head had to explain this after the registers had been taken and was quite the coincidence. While the fire service opened the buildings soon after lunch break finished, they were still on site at the end of the day over an hour later.