There was some limited 10-car operation using 456s before that - but only Platform 5 on the main line suburban side could take them until the rebuilding
This was strictly designed and limited to those Main suburban trains that were booked in to higher platforms, #5 being the lowest of, and revolved mainly around those Guildford New Line services that ran non stop between Surbiton and Waterloo (and vice versa), and a small number of (diagram) associated pre a.m. peak and post p.m. peak services. These were given 9xxx identity numbers to aid signallers and prevent the accidental diversion of any of same in to p1-4. I can list all such trains if anyone is interested.
There were some 10car workings of pairs of 458s on the Windsor side before August 2017 too. Although mainly concentrated on Reading services there were a few all station stoppers inwards from Staines that were formed as 10cars.
From memory there were 455+456 formations at least decade ago, but for a while 455+ 2x456 = 8 cars were common, so date when some became 10car is bit of a blur
In reference to that which I have said in response to norbitonflyer (above), but also the case of 10 car 458/5, both scenarios became part of the permanent plan commencing with the May 2015 timetable change, although will have operated, in part(s), as the first units became available for service, in the weeks/months* prior to that under STP (Short term plan) basis. The 485/5 being limited to six pairs at that date, working a number of Brentford loop/Weybridge diagrams and two Windsor & E diagrams, and diagram associated journeys at start and finish of the day.
At this date the 458/5 conversion was still in progress and infrastructure for 10 car operation was still also a work in progress, so there were limits as to where 10 cars could operate in service.
* The original planned timescale for 458/5 introduction was March 2014 to May 2015, but this was delayed by a number of things, not least the tin worm found in a number of 460 vehicles that formed the basis of the first units to enter service.
MODS: Please move to the main 'Historical' area if you feel that's a better place. Have left this discussion here for now, in order that other '701' theme contributors can easily see there is a separate place for non 701 10 car items.