There’s a 22:15 arrival into Manchester Piccadilly from Carmarthen that forms a 22:14 to Chester using the same unit
Yes, there are no rules about minimum turnarounds at Piccadilly. In any case this one doesn't involve a turnaround as it runs into platform 14 and continues in the same direction.
Really I wonder more why it isn't advertised as a direct service, as there are some flows (e.g. Crewe, Wilmslow & Stockport to Oxford Rd, Newton-le-Willows, Earlestown and possibly Warrington) where it's the fastest journey opportunity, especially at that time of night. The fact it's split into two services means there isn't an official connection between the two.
Another example at Piccadilly is the Hadfield service, which has an 80 minute journey time out and back, with 4 reversals on the minimum 3 minute allowance, followed by a 10 minute turnaround. It's even less during the peaks, when additional stops are added at Gorton and Fairfield.