Chemistry[edit]
A
lithium-titanate battery is a modified lithium-ion battery that uses lithium-titanate
nanocrystals, instead of
carbon, on the surface of its
anode. This gives the anode a surface area of about 100 square meters per gram, compared with 3 square meters per gram for carbon, allowing electrons to enter and leave the anode quickly. Also, the redox potential of Li+ intercalation into titanium oxides is more positive than that of Li+ intercalation into graphite. This leads to fast charging (higher charging current) being much safer in the case of the titanate, than in the case of carbon, since lithium dendrites are less likely to form in the former case.
[11] Lithium-titanate cells last for 3000 to 7000 charge cycles;
[12] a life cycle of ~1000 cycles before reaching 80% capacity is possible when charged and discharged at 55 °C (131 °F), rather than the standard 25 °C (77 °F).
[13]
A disadvantage of lithium-titanate batteries is their lower inherent voltage (2.4 V), which leads to a lower
specific energy (about 30–110 Wh/kg
[1]) than conventional lithium-ion battery technologies, which have an inherent voltage of 3.7 V.
[14] Some lithium-titanate batteries, however, have an
volumetric energy density of up to 177 Wh/L.
[1]