BS1363 requires 240V (no, not 230V, it never has been)
BS1363 is a standard for plugs and sockets, it doesn't specify the voltage output by the sockets.
The UK standard mains voltage is 230V -6% +10% and has been for many years after harmonisation across Europe. Voltages between 216V and 253V are within specification. BS1363 plugs and sockets are approved for 250V use and below (although this number is derived from the requirements in BS EN 60664-1 and the nominal supply voltage, so they should probably actually be marked as 253.6V rather than 250V).
If these cleaners sockets are live and accessible to the public, even with a sign saying "not for public use", they should conform to the standard electricity supply specifications - especially over/under voltage, frequency and stability. A simple sticker is not a sufficient control measure if the supply would be dangerous to use with domestic equipment - alternative means of control, such as isolation when not in a depot - would need to be employed. However, it the supply is safe to use, but unpredictable - e.g. turning on/off through neutral sections; or extremely low current capability such that it would trip out if common equipment was connected, then a simple sign is sufficient.
If a connection that is only accessible to authorised users was required, there are alternative connectors available that most people don't have access to (such as the T-shaped earth pins, commonly found in hospitals), or the connectors could be installed behind a lockable panel.