The short answer is - yes, you could give a positive for opiates but unless you ate a whole kilo in weight of poppy seeds the chances of getting any contaminated poppy seeds and therefore enough of a dose to register then it should not be a problem. In theory one poppy seed in a million is contaminated. But what are the chances of you having enough of the contaminated seeds in your 2 slices of bread?
Whilst Snopes is a good source of a lot of info the fact that the seed pods are the only source of the opiate, not the seed, and that the seeds are washed and processed to remove any possible contamination from the seed pod the likelihood of a positive is miniscule.
Is it worth letting them know? Not much you can do about it now as the lab will have the specimen. No matter what you do or say now, after the fact, is totally irrelevant. Imagine the phone call . . . .
"Hello is that the lab?"
"Yes"
"Well, I've got a Mr Smith who remembers he has eaten poppy seeds so it might show up in his urine that you have for testing."
"Thanks for letting us know, we were wondering why it was so high."
"So he's OK for employment?"
"Well we thought he was a drug user but now you've explained he eats bread he should be fine, go ahead."
"Great, he will be pleased, thank you."