Could you use an off peak ticket from Glasgow Central with an effective Monday-Friday time restriction of "not valid 0430-0859" on the 0422 TPE southbound Anglo Scottish service?
I can't see any specific tickets, but which one are you talking about?
A Glasgow to London off peak ticket (via West Coast) will not be allowed on trains arriving in London Euston after 04:29 and before 10:05 Monday to Thursday, so not allowed on the 0428 to Euston, but is allowed on the 0422 (and any other train) as they aren't going to London Euston.
On the other hand a normal Glasgow to Manchester off peak ticket would be allowed on both the 0422 and 0428 (it's simply "Not valid on trains scheduled to depart before 04:15.").
The Transpennine only one is not valid on services timed to depart between 04:29 and 09:00, which should be OK on the 0422, but not the 0745 to Liverpool.
A Glasgow to Carlisle off peak return is not valid on trains timed to depart after 04:29 and before 09:00, so again OK on the 0422 and 0428, but not the 0533.