To answer the OP question the answer is that most of the network was developed before metrication in the UK. The cost of converting existing drawings, signs and everything associated would be massive, and probably wouldnt bring enough benefits to justify the cost.
Realistically I suspect this will be the situation for many years to come, I am not going to say 'forever' but probably way beyond any look ahead in terms of upgrades plans etc.
Metrication has been a long hard slog in the UK, there is so much reliance on imperial measurements in everyday life, and they are part of our culture (for example 'going for a pint', thats never 'going to become going for a 660ml' and pub goers would be upset if the 'pint' was reduced to 'half a litre').
During the 70s which were an inflationary period anyway people assumed, in some cases quite rightly, that metrication and decimalisation was an excuse for price increase by stealth.
I went to the school in the 60's and was taught imperial measurements, although I then learnt metric when I embarked on my engineering career in the 70's. I have to be honest, I still think in imperial, and convert to or from metric in my mind when discussing things, and I in common with most of my generation don't mind doing that. Like it or not we are going to be using both systems for many years to come