Here's the full list to save anyone having to look it up:
Diesel mechanical / hydraulic multiple unit sets 100 199
Diesel electric multiple unit sets 200 299
Diesel multiple unit sets
600 699
d.c. electric multiple unit sets 400 599
a.c. and a.c. / d.c. electric multiple unit sets 300 399
a.c. and a.c. / d.c. electric multiple unit sets 700 799
High speed multiple unit / fixed formation sets 800 899
Infrastructure maintenance / non-passenger multiple unit / fixed formation sets
900 999
That's the same order as given in table A.5 of GMRT2453, you'll see that 6XX is for new DMUs of unspecified type.
https://www.rssb.co.uk/rgs/standards/GMRT2453 Iss 2.pdf