Yes, the UK may be a relatively smaller polluter, but the UK government has recently committed the UK to zero carbon by 2050. These units will not help achieve that. There seems to be a consensus on this thread that acquiring this large fleet of 197s will delay electrification / change to other less-polluting propulsion modes than would otherwise have been the case. They will be running under the wires for part of some of their routes from when they are introduced into service, and this will only increase over the next few decades - noting comments made about likelihood of N Wales, etc being electrified.
And countries that generate larger proportions of carbon emissions are getting to grips with the issues, and driving down their carbon emissions. The Chinese government has recently given ambitious
emissions reduction targets to major energy-consuming industries for emissions to peak by 2025, to achieve “steady” reductions by 2030 and “substantial” reductions by 2035. In response the steel industry which is responsible for more than 30% of total coal use in China, has said that its CO2 emissions would peak before 2025 and fall 30% from the peak by 2030. Doubtless such announcements will be greeted by some with a soupcon of scepticism. Time will tell.
I didn't assume anything about the ease or otherwise of changing mode of operation, rather I stated what I concluded from what I had read on this matter on this thread (eg posts #816, #910), and elsewhere. And yes, it's noted that some consider it 'should' be relatively easy - but the class 230 / 769 experiences (using 'proven' technologies) perhaps suggests that it may not be that straight-forward, especially given the constraints of the loading gauge over which much of the fleet will operate.