According to the Sectional Appendix, Salford Central Platforms 1 & 2 (on the Salford lines) are 136m and 140m. So very nearly long enough for a 6-car 323 (140.4m), especially considering the doors are at thirds.
I believe you are referring to the new (not yet in use) platforms on the Liverpool and Ordsall Chord lines. There are no plans for Northern EMUs to use those platforms.
I think TfGM still thinks they existing platforms are too short, they want to extend them and add 3 platforms. I thought normally platforms are at least 5m longer than rolling stock? Extending all platforms to allow 6 coach EMUs would require funding even if in low tens of millions.
I don't think there is the demand for 6 coach EMUs from Preston to Victoria. The Castlefield bottleneck will limit services to Piccadilly and Oxford Road which will continue to be more popular stations. Bolton-Victoria has Wigan and Blackburn services too. 319s or 323s on Preston-Victoria and 769s on Wigan-Victoria via Bolton will be a significant improvement.
An issue with 6 coach units is platform length south of Piccadilly and Victoria. When Stalybridge is rebuilt (again) and wired will the bay platform for terminating services from Victoria be long enough? Hazel Grove would be another choice but that would reduce flexibility for timetabling because Woodsmoor and Davenport cannot fit 6 coaches. Manchester Airport station timetabling relies on a lot of double stacking and 6 coach units would reduce options.