They will be AC only, but like any other modern stock there will be nothing stopping them being converted to DC in the future.
I don't know of what orders for "dual voltage" stock there are going to be anyway, beyond the Thameslink stock and any more for London Overground. Merseyrail may go for dual voltage stock, but 319s aren't suitable for that anyway, plus they want new stock, not slightly newer stock. The only other potential DV order in future is in relation to link up between the GW electrification and the SR electrified network, but by the time that is needed the 319s will be getting on even more and already allocate (even more stupid would be to order new AC only trains and store the 319s until a future time when more DV units may be needed).
It has to be remembered that all stock since privatisation has been dual voltage, even if not fitted with all the equipment. As has been said, modern electronics makes it easy. Ordering stock as AC only has no real advantage, you only really save on the lack of shoe gear, but most "dual voltage" stock doesn't have that anyway.
Are the 350/1s actually fitted with shoe gear anyway? I thought it was removed after they finished on the Brighton-MKC service?