Why is this - last one built?
Yup last built though no longer the last in the TOPS numbers for the class as there is a 91132 which was originally 91023 but gained a different number (rather than just having 100 added as the rest) after refurbishment due to it being involved in both Great Heck and Hatfield accidents.
On the compatibility:
Mark 4s have been run with Class 89 and 90. Presumably they could also therefore work with 86 and 87?
As far as I'm aware Mark 4s could be hauled by any locomotive on the network (electric or diesel) as long as there is a TSOE vehicle (that's the vehicle that is next to the 91 in a IC225 formation) or a DVT (with pointy end facing outwards) in the formation. Of course only locomotives equipped with TDM could talk to the DVT for use in push/pull operations (or AAR locomotives if you converted the Mark 4s).