Sorry to disappoint you, but as someone who drives both on a daily basis, the 800 is much quicker up to 20 in Diesel mode but then the engines rate back and then it has acceleration akin to a turbo. For the first mile the 800 would stay ahead but then the HST would wind it in very quickly. To give you an example, leave Honeybourne towards London climbing Campden bank and you will just about see 65 in an 800 as you enter Campden tunnel, in a HST you have notched back best part of a mile before the tunnel entrance in order to avoid going over the 75 linespeed. Conversely, leave Paddington on the Down main and as soon as the 50 eases at Ladbroke Grove you will find that a healthy HST will be doing around 90 passing Ealing Broadway whereas an 800 in diesel will be doing low 80's. In electric mode however, the 800 is just about hitting 100 as the linespeed lifts to 125 at Acton.
Bear in mind that you as a passenger do not know the status of the train in which you are travelling, are you aware that 800's when working in pairs can run in either diesel, electric or a combination where one set is electric and the other diesel. This last mode is the only one that would make sense regarding your perception of fast in diesel mode if you happened to be sat in one of the sets running in diesel and the other ably assisting in electric mode. As my depot diagrams do not currently have any 10 car diagrams I cannot offer an example of performance when operating in dual mode.